ISSN (0970-2083)

ADSORPTION OF REACTIVE DYE USING AGRICULTURAL WASTE - A KINETIC APPROACH

A. Geetha1*, A. Ramados2 and G. Sudha Priya3

1Department of Chemistry, S.A. Engineering College, Chennai, T.N., India

2JSW, Bellary, Karnataka, India

3Department of Civil Engineering, S.A. Engineering College, Chennai, T.N., India

*Corresponding Author:
A. Geetha
E-mail: cgeetha22@gmail.com

Received date: 10 February, 2014; Accepted date: 15 March, 2014

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Abstract

This study was designed to investigate the removal of reactive violet 48 from wastewater using Commercial activated carbon and Coir pith activated carbon. Its adsorption capacity has been tested for the decolourization of waste water containing reactive violet 48. The effect of system variables such as concentration, temperature, contact time and pH were studied. The adsorption data follow Langmuir model as well as Freundlich model.

Keywords

Commercial activated carbon, Coir pith activated carbon, Adsorption, Aqueous dye solution

Introduction

Waste water generated by the dye production industry and many other industries which use dyes and pigments is characteristically high in both color and organic content. About 10,000 different commercial dyes and pigments exist, and over 7 x 105 tons are produced annually world wide. It was estimated that about 10-15% of these dyes are released in effluents during dyeing processes (Papic et al. 2004).

The removal of dyes from industrial effluent is a major problem as Government legislation becomes more stringent. Discharge of dye bearing wastewater into natural streams from textile, paper, carpet and printing industries has created significant concern, as dyes impart toxicity and visibility (ICI Watercare, 1991).

Various techniques, such as chemical coagulation (Stephenson et al. 1996) (Niranjan and Karthikeyan, 1992) biosorption (Low et al. 1993) oxidation using ozone (Churchley, 1994), membrane separation (Grossley, 1994) and adsorption have been generally employed for colour removal. Adsorption is one of the most effective physical processes for the removal of dyes from wastewater. Most conventional adsorption systems use activated carbon which is expensive and necessitates regeneration ( Mckay, 1982). Several researchers have investigated the alternative adsorbent materials that though less efficient involve lower costs. Among the studies alternative materials are lignite (Allen et al.1989), wood (Poots et al. 1978), flyash (Khare et al. 1988), coal (Gupta et al. 1990), boiler bottom ash (Mall and Upadhyay, 1995), rice husk (Lodha et al. 1997) and withered Psidium guyava Leaves (Singh and Srivastava, 1999)

Hence we undertook an attempt to prepare low cost carbon from the locally available natural material like coir pith. The characteristics of the carbons and applicabilities have been compared with that of Commercial activated carbon(CAC). The effect of various parameters such as initial dye concentration, temperature and pH has been investigated.

Materials and Methods

Preparation of Coir pith Activated Carbon (CPAC)

Coir pith activated carbon (CPAC) was prepared by treating four parts with two parts of concentrated sulphuric acid and keeping it in an air oven at 140°C - 170°C for 24 hours. The carbonized material was filtered and washed with water to remove the excess acid and dried at 105 -110°C. The materials were grounded well and sieved to an average diameter of 0.5 mm (20- 50 ASTM) was used for further studies.

Preparation of dye solution

Accurately 100 mg of Reactive violet 48 was weighed and dissolved in 100 mL of water to get 1000 ppm dye solution.

Batch type experiments Effect of time and initial dye concentration on the dye removal

Appropriate amount of stock solutions were diluted and were made up to 1000 mL to get 20, 40, 60, 80 and 100 ppm of dye solutions. Batch experiments were carried out by shaking 100 mL of dye solution with 0.1 g of the adsorbent in glass stopered conical flasks at a temperature of 20°C at the rate of 130 rpm. The effect of various parameters such as initial dye concentration, contact time and pH on the adsorption process was investigated. The progress of adsorption during the experiments was determined by removing flasks after desired contact time, centrifuging and analyzing the supernatant spectrophotometrically for dye concentration. The absorbance was measured at 408 nm against a blank.

Effect of pH on the dye removal

Effect of pH on the dye removal was found out by the following method. About 100 mL of aqueous dye solution containing 20 ppm of dye solution was taken in separate conical flasks. The pH of the solutions were maintained as 2,4,6,8, and 10 respectively using 0.1N NaOH and HCl solutions.

Results and Discussion

The characteristics of the coir pith activated carbon (CPAC) obtained by agglomeration are presented in Table 1, Except for a decrease in the surface area, all characteristics of the coir pith was similar to that of the commercial activated carbon. The coir pith activated carbon (CPAC) with a density of 0.64 g/cm3, can be suitably employed in a continuous treatment process.

icontrolpollution-Physicochemical-Characterization-CPAC

Table 1: Physicochemical Characterization of CAC and CPAC

Effect of initial dye concentration and contact time

The effect of initial dye concentration and contact time on the removal of reactive violet 48 is shown in Fig.1 and 2. From the Figure, it was evident that the removal of dye increased with decreasing dye concentration. Adsorption increased with an increase in contact time. It was found that equilibrium was attained at 40 min. Similar result was obtained in the removal of reactive dye using adsorbents CAC and CPAC were found to be 70% and 50% respectively, at 40 min equilibration time and at 20 ppm initial dye concentration.

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Figure 1

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Figure 2

Effect of pH

The removal of dyes as a function of pH is shown in Fig. 3. the removal of dye by CAC and CPAC were found to be a maximum in the acidic pH range of 1-3. It was observed that CAC and CPAC have removed dye to a maximum of 89% and 82% at pH 2. The pH value of the solution plays an important role in the whole adsorption process and particularly on the adsorption capacity. Similar observations have been reported by other workers for adsorption of reactive dyes indicating that the carbon has a net positive charge on its surface (Bousher et al. 1997).

icontrolpollution-Effect-Adsorption-dye

Figure 3: Effect of pH on the Adsorption of dye using CAC and CPAC

Adsorption Isotherms

The equilibrium data for the system undertaken has been observed and analyzed Langmuir isotherm equation.

image

Where, Ce is the equilibrium concentration (mg/ L), qe is the amount of the dye adsorbed (mg/g), Q° and b are Langmuir constants related to adsorption capacity and energy of adsorption respectively. The linear plot of Ce/qe vs Ce shows that the adsorption follows Fig. 4 and 5. The present investigation was confirmed by obtaining the value of Q° and b using regression analysis of equilibrium data and found 44.643 & 21.978 mg/g for Q° and 0.0692 & 1.001 (lmg- 1) for b respectively (Table 2). A linear plot confirms the applicability of Langmuir isotherm.

icontrolpollution-Langmuir-adsorption-Reactive

Figure 4: Langmuir Plot for the adsorption of Reactive violet 48 on CAC

icontrolpollution-Langmuir-adsorption-violet

Figure 5: Langmuir Plot for the adsorption of Reactive violet 48 on CPAC

icontrolpollution-Intercept-Langmuir-Freundlich

Table 2: Intercept and slope values of Langmuir and Freundlich isotherm for CAC & CPAC

Freundlich adsorption isotherms

The isotherm has been proposed by Freundlich for dilute and moderately dilute solutions. It is represented empirically by the expression.

image

The values of 1/n and kf are determined from the slope and intercept of the curves, which was obtained by plotting log qe vs log Ce, where k f is the measure of sorption capacity (mg/g) and 1/n is the measure of sorption intensity (Vaishya and Prasad, 1991). The empirical constants kf and 1/n determined from the intercept and the slope of the straight line are furnished in Table 2. The values of 1/n lie between 0.3 and 0.2 which represents good sorption potential of the sorbent (Fig. 6 and 7). The linear plot confirms the applicability of Freundlich isotherm.

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Figure 6: Freundlich plot for the adsorption of Reactive violet 48 on CAC

icontrolpollution-Freundlich-Reactive-violet

Figure 7: Freundlich plot for the adsorption of Reactive violet 48 on CPAC

Conclusion

The experimental results showed that activated carbon prepared from coir pith was a suitable adsorbent for removal of reactive dyes from both synthetic and textile effluent. In batch studies, the adsorption increased with an increase of contact time and decreased with an increase in solute concentration. Removal of dyes was higher at the acidic pH range. The results showed that the carbon affinity was higher for Reactive violet 48.

References

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